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Samuel D. Humphrey

History of Iodine.--This is one of the simple chemical bodies which was discovered in 1812 by M. Courtois, of Paris, a manufacturer of saltpetre, who found it in the mother-water of that salt. Its properties were first studied into by M. Gay Lussac. It partakes much of the nature of chlorine and bromine. Its affinity for other substances is so powerful as to prevent it from existing in an isolated state. It occurs combined with potassium and sodium in many mineral waters, such as the brine spring of Ashby-de-la-Zouche, and other strongly saline springs.

This process is patented in the United States, by J. A. Whipple, of Boston, and of course no honorable person will use it for his own benefit without purchasing a right.

History.--The Swedish chemist, Scheele, in 1774, while examining the action of hydrochloric acid on peroxide of manganese, first noticed this element. He called it dephlogisticated muriatic acid. It was afterwards, by the French nomenclaturists, termed oxygenated muriatic acid, conceiving it to be a compound of oxygen and muriatic acid. This view of its notice was corrected by Sir H. Davy (in 1809), who gave it the present name. In 1840-41, this gas vas employed for accelerating the operation of light upon the iodized Daguerreotype plate.

This process is also patented, and the remarks on the preceding subject will apply in this case. The plate is prepared and exposed as in the usual method of the Daguerreotype. A white back-ground is employed. Let the head of the sitter come in the middle of the plate, and before exposing it to the vapors of mercury, put a small mat or diaphragm, having a small hole through it, over or directly on the surface of the plate. This diaphragm should be bevelled, and the bevel should be towards the surface of the plate; this, in order to prevent too sharp a line on the impression.

Cyanide of Potassium.--This important article is worthy the undivided attention of every Daguerreotypist. I here give Mr. Smee's process for its preparation. This is from that author's work entitled, "Electro Metallurgy," American edition:

This subject is worthy the attention of every operator. The following process is so plain and easy of trial that any Daguerreotypist can try it. This is as given by Mr. James Campbell, and was published in Humphrey's Journal of the Daguerreotype and Photographic Arts, vol. 5, page 11. Mr. Campbell has done much to further the process announced by M. Neipce, and his experiments have proved highly successful.

The following is submitted as worthy of trial:

Hyposulphite of Soda.--This salt forms one of the important chemicals for the Daguerreotype operator. Its application to this art is of an interesting nature. It is used to dissolve the sensitive salt of silver which remains unchanged during the exposure in the camera. It has the property of readily dissolving the chloride, bromide and iodide of silver. It should be pure and free from sulphuret of sodium; should this last be present, it will cause brown spots of sulphurated silver upon the Daguerreotype impression.

I have produced some interesting specimens of the Daguerreotypic art, by exposing in the camera only a portion of the sensitive plate to the action of light. When on the exposed portion an image is formed, then taking the tablet into the dark room, change ends and expose the sensitive portion, and produce another image, developing as usual. This plan is adapted for taking likenesses for lockets. Two images can be presented as sitting side by side, by covering half the plate with black paper, and exposing as before.

Remarks on the Accelerating substances Used in the Daguerreotype.--I have now arrived at a point in this work, where the eye of the Daguerreotype public will intently search for something new. This search will prove in vain, at least so far as regards those who have enjoyed and embraced the opportunities for studying the principles of our art.

Regarding specks from bad water, I would remark that gilding should be made only with distilled water. Thus made, it produces very little deposit, even by long keeping. It therefore preserves its original strength, and works with great uniformity.

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