Samuel D. Humphrey

To any desired quantity of chloride of silver in water add, little by little, cyanide of potassium, shaking well at each addition, until all the cyanide is dissolved. Continue this operation, and add the cyanide, until all the precipitate is taken up and held in solution.

This solution is now ready for the plate-cup. Enough water may be added to cover any sized plate when held perpendicular in the cup. The strength of the solution may be kept up by occasionally adding the chloride of silver and cyanide of potassium. There should alway be a very little excess of the cyanide.

Light--Optics--Solar Spectrum--Decomposition of Light--Light, Heat, and Actinism--Blue Paper and Color for the Walls of the Operating Room--Proportions of Light, Heat, and Actinism composing a Sunbeam--Refraction--Reflection--Lenses--Copying Spherical Aberration--Chromatic Aberration.

The following process possesses some interest, and is worthy a trial from operators. M. Natterer, of Vienna, discovered a process for obtaining proofs on iodized plates with the chloride of sulphur, without the use of mercury.

It is necessary, first of all, to know that you have a chemical which is capable of producing good results when in skillful hands. For this reason it is best to prepare your own quick, after some formula which is known to be good. Those quick-stuffs which contain chloride of iodine are noted for their depth of tone while they probably operate with less uniformity than those which are destitute of it. For operating under ordinary circumstances, especially with an inferior light, probably no accelerator is more quick and sure than Wolcott's.

Polishing the Daguerreotype Plate--Buffing the Plate--Coating the Plate--Exposure of the Plate in the Camera--Position--Developing the Daguerreotype--Exposure to Mercury--Removing the Coating--Gilding or fixing the Image--Coloring Daguerreotype.

First of all, cleanliness should be observed. When there is dust or dirt about your room, particularly about the work-bench, failures will be frequent; for the smallest particles of rotten-stone, when allowed to come in contact with the buffs, will produce scratches on the surface of the plate, which very much injures the operation, and often causes failures.

Dust flying about the room is injurious, if allowed to fall on the plate, either before or after it has been coated, as it causes black spots which cannot be removed.

An article so extensively used in the practice of the Daguerreotypic art as Bromine, is deserving of especial attention, and accordingly every person should endeavor to make himself familiar with its properties and applications.

I am indebted to Mr. J. H. Fitzgibbons for the following process, which he employed in producing the excellent specimens he exhibited at the Crystal Palace:

History of Iodine.--This is one of the simple chemical bodies which was discovered in 1812 by M. Courtois, of Paris, a manufacturer of saltpetre, who found it in the mother-water of that salt. Its properties were first studied into by M. Gay Lussac. It partakes much of the nature of chlorine and bromine. Its affinity for other substances is so powerful as to prevent it from existing in an isolated state. It occurs combined with potassium and sodium in many mineral waters, such as the brine spring of Ashby-de-la-Zouche, and other strongly saline springs.

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